锂离子电池正极材料第一原理计算研究

利用第一原理计算方法可分析和预测锂-金属氧化物电池正极材料在Li离子嵌入脱出过程中的电势和稳定性等性能。本文详细介绍了第一原理计算方法的理论背景以及目前LiCoO2正极材料计算研究的现状。利用此方法对LiNiO2及多组分材料掺杂进行研究是今后工作的重点。     

Sensing, modeling and control for laser-based additive manufacturing

Laser-Based Additive Manufacturing (LBAM) is a promising manufacturing technology that can be widely applied to part preparation, surface modification, and Solid Freeform Fabrication (SFF). A large number of parameters govern the LBAM process. These parameters are sensitive to the environmental variations, and they also influence each other. This paper introduces the research work in RCAM on improving the performance of the LBAM process. Metal powder delivery real-time sensing and control is studied to achieve a controllable powder delivery for fabrication of functionally graded material. A closed-loop control system based on infrared image sensing is built for control of the heat input and size of the molten pool in the LBAM process. The closed-loop control results show a great improvement in the geometrical accuracy of the built features. A three-dimensional finite element model is also established to explore the thermal behavior of the molten pool in the closed-loop controlled LBAM process.     

多元酚——甲醛树脂中游离酚,游离醛含量的测定

多元酚－－甲醛树脂是本院开发的热固粘接剂新产品，本文给出了这一产品技术指标中游离酚、游离醛含量的测定方法，并对方法进行了讨论。     

无垫片焊接密封法兰计算方法的讨论

应用华脱尔斯法建立了内、外焊唇焊接法兰结构的力学模型,在相同设计条件和材料状况下,进行了内、外焊唇结构法兰的受力分析、设计计算和结构尺寸对比。笔者认为:如果设计计算成立且焊接条件允许,内焊唇结构的法兰比外焊唇结构的法兰螺栓载荷减小,截面积减少,法兰直径和厚度也相应大幅降低。     

低醛化脲醛树脂的合成与性能研究

在低物质的量比条件下，分析讨论了脲醛胶的各项力学性能，甲醛释放机理，通过研究表明：选择适合的物质的量比（F／U≤1.3)、改造合成工艺、添加偶联螯合剂（1.0%)等，可生产出综合性能较好的低毒脲醛胶，胶合板甲醛释发量达到E1级（≤1.5mg/L），力学性能符合GB／T9846－1988及GB／T15104－1994标准要求。     

Effect of surface free energy on the adhesion of biofouling and crystalline fouling

Pipelines and heat exchangers using seawater as coolant suffer from biofouling. Biofouling not only reduces heat transfer performance significantly, but also causes considerable pressure drop, calling for higher pumping requirements. It would be much more desirable if surfaces with an inherently lower stickability for biofouling could be developed. In this paper, a cost-effective autocatalytic graded Ni-Cu-P-PTFE composite coating with corrosion-resistant properties was applied to reduce biofouling formation. The experimental results showed that the surface free energy of the Ni-Cu-P-PTFE coatings, which were altered by changing the PTFE content in the coatings, had a significant influence on the adhesion of microbial and mineral deposits. The Ni-Cu-P-PTFE coatings with defined surface free energy reduced the adhesion of these deposits significantly. The anti-bacterial mechanism of the composite coatings was explained with the extended DLVO theory.     

绿色节能脲醛树脂粘合剂的生产新方法

介绍了低游离甲醛含量的低醛/尿摩尔比脲醛树脂木材粘合剂的生产新方法。利用控制不同反应阶段不同工艺条件,使整个生产周期缩短20%,并充分利用反应热,使能耗降低。     

双季戊四醇收率与反应条件依赖关系研究

利用均匀设计法，通过少量实验，使用计算机回归出双季戊四醇收率与反应条件间的依赖关系：Ｙ＝４．１４１８＋０．０８９ｘ＿１－１０．０８ｘ＿２＋８３．０１８ｘ＿３－０．１２９ｘ＿４－２９．６３８ｘ，其表明增加反应温度和降低甲醛与乙醛配比都可以增加双季戊四醇的收率，结果与实验相吻合。用回归方程得到的优化条件进行实验得到的双季戊四醇收率为２５．４％，与预测值很接近。     

The role of the surface free energy in the selection of a suitable excipient in the course of a wet-granulation method

Pellets containing metronidazole were produced in a centrifugal granulator, with hydroxypropylcellulose (Klucel LF®) as binding agent, and corn starch, microcrystalline cellulose (Vivapur 101®) and lactose as excipients. The wettability of the pharmaceutical powders was assessed by means of contact angle measurements, and the dispersive and polar surface energies were determined. The spreading coefficients, the work of adhesion and the work of cohesion were calculated and correlated with the pellet properties (friability, bulk and tapped density, and porosity). The aim was to investigate the role of the surface free energy of one- and two-component powder compositions in pellet production. The interactions between the particles were found to be connected with the measured pellet parameters. It was concluded that, in the course of the growth of the pellets, the particle sizes of the pharmaceutical powders and the interactions between them are important. If the work of cohesion of the binder is lower than the work of cohesion of the substrate and the work of adhesion, then the optimal amount of the binding agent is that which coats the particles uniformly in minimal quantity and in continuous layer.     

木材用交联型醋丙胶粘剂的研制

研制一种由醋酸乙烯、丙烯酸丁酯、特种单体共聚而成的水性交联型环保胶粘剂以替代目前广泛使用的氨基树脂,适应绿色环保要求。